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The problem is really that you cannot loop round and carry out a series of actions against each instance of a collection. So you can populate a reminder with data automatically in a process, but you still need to 'do' this action several time. There is one place where LANDesk did implement this looping facility in requests when you have a service catalogue bundle, but unfortunately it wasn't implemented as a generic feature. It would be very handy if it was.
As an alternative you might want to look at the Add CC action which might do what you are after - this automatically notifies a list of people when the raise user gets an email.