You should be able to boot to WinPE and run the same Windows capture template using ImageW to capture Linux. ImageW is a sector based tool, so it does not care what OS is on the system; it will simply make an exact copy of it.
The deployment side will be a bit more in depth as you will have to configure the boot loader and deal with drivers. I have not done this so I cannot speak to this point but I know it is possible.
Hope this helps,