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In order to achieve your goal, you have 2 ways;
1- you need to do it through the SQL query defined in the DataSet showing the values.
Example; "select * from computer order by Computer_Idn ASC" will show a different order than "select * from computer order by Computer_Idn DSC" on the report listing the computers
2- right-click on the top column (see red arrow in the printscreen below) > properties > choose Sorting Tab and from there, I think you will understand. These sorting method supersedes the method I described before.
I hope it will help,
Good luck, Sebastien.